ChemicalBook > CAS DataBase List > (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE

(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE

Product Name
(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE
CAS No.
148461-14-7
Chemical Name
(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE
Synonyms
(S)-iPr-Phox;Diphenylphosphinophenylmethylethyldihydrooxazole;(S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-;)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline;(S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydroo;(-)(4S)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(2-PROPYL)OXAZOLINE;(S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYL-2-OXAZOLINE;2-(2-Diphenylphosphanyl-phenyl)-4-isopropyl-4,5-dihydro-oxazole;(-)(4S)-2-[2-(Diphenylphosphino)phenyl]-4-(2-propyl)oxazoline 97%;(S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydrooxazole
CBNumber
CB6159670
Molecular Formula
C24H24NOP
Formula Weight
373.43
MOL File
148461-14-7.mol
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(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Property

Melting point:
85-90 °C
alpha 
-44° (c 1.4, CHCl3)
Boiling point:
492.7±28.0 °C(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
4.31±0.70(Predicted)
form 
Powder
color 
white
optical activity
[α]20/D 48±3°, c = 1% in chloroform
Sensitive 
air sensitive
BRN 
5879302
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
37/39-26-24/25
WGK Germany 
3
F 
10-23
Hazard Note 
Irritant
HS Code 
29349990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Strem Chemicals
Product number
15-1822
Product name
(S)-(-)-2-[(2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole, 98% (S)-iPr-PHOX
Packaging
50mg
Price
$103
Updated
2024/03/01
Strem Chemicals
Product number
15-1822
Product name
(S)-(-)-2-[(2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole, 98% (S)-iPr-PHOX
Packaging
250mg
Price
$361
Updated
2024/03/01
Strem Chemicals
Product number
15-1822
Product name
(S)-(-)-2-[(2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole, 98% (S)-iPr-PHOX
Packaging
1g
Price
$1084
Updated
2024/03/01
ChemScene
Product number
CS-W011786
Product name
(S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydrooxazole
Purity
>97.0%
Packaging
250mg
Price
$68
Updated
2021/12/16
AK Scientific
Product number
5316AQ
Product name
(S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole
Packaging
250mg
Price
$599.6
Updated
2021/12/16
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(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Chemical Properties,Usage,Production

Chemical Properties

White crystalline powder

Reactions

  1. Chiral ligand used in the asymmetric reduction of highly substituted olefins.
  2. Chiral ligand used in the enantioselective Heck reaction. The success of the reaction is due to the fact that the catalytic system does not promote double bond isomerization.
  3. Chiral ligand used in the entantioselective palladium-catalyzed allylic substitution of sodium benzotriazole.
  4. Decarboxylative allylic alkylation.

(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Preparation Products And Raw materials

Raw materials

Preparation Products

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(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Suppliers

Belgium 1 China 76 Germany 3 Japan 1 Switzerland 1 United Kingdom 2 United States 4 Global 88
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View Lastest Price from (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE manufacturers

XINXIANG RUNYU MATERIAL CO., LTD.
Product
(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE 148461-14-7
Price
US $0.00-0.00/g
Min. Order
1g
Purity
97%
Supply Ability
5kg
Release date
2024-03-22
Career Henan Chemical Co
Product
(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE 148461-14-7
Price
US $3.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100kg
Release date
2019-07-10

148461-14-7, (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLERelated Search:

Phenyl phosphine Oxazoline (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE (4R)-(+)-4,5-DIHYDRO-2-(2'-(DIPHENYLPHOSPHINO)PHENYL)-4-ISOPROPYLOXAZOLE (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE DIPHENYL(P-TOLYL)PHOSPHINE

  • (S)-(-)-2-[(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE
  • (S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-ISOPROPYL)-4,5-DIHYDROOXAZOLE
  • (S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE
  • (S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4,5-DIHYDRO-4-ISOPROPYLOXAZOLE
  • (S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYL-2-OXAZOLINE
  • (-)(4S)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(2-PROPYL)OXAZOLINE
  • (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE
  • (S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-
  • (4S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydrooxazole
  • Diphenylphosphinophenylmethylethyldihydrooxazole
  • (4S)-(-)-4,5-Dihydro-2-[2'-(diphenylphosphino)phenyl]-4-isopropyloxazole,98%
  • (S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole,98%
  • (-)(4S)-2-[2-(Diphenylphosphino)phenyl]-4-(2-propyl)oxazoline 97%
  • 2-(2-Diphenylphosphanyl-phenyl)-4-isopropyl-4,5-dihydro-oxazole
  • (S)-(-)-2-[(2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE,98%(S)-IPR-PHOX
  • (S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydrooxazole
  • (4S)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydro-4-(1-Methylethyl)-Oxazole
  • (4S)-(-)-2-(2-Diphenylphosphanyl-phenyl)-4-isopropyl-4,5-dihydro-oxazole
  • )-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline
  • (S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline >=97.0% (CHN)
  • [2-[(4S)-4-isopropyl-4,5-Dihydrooxazol-2-yl]phenyl]-diphenyl-phosphane
  • Oxazole,2-[2-(diphenylphosphino)phenyl]-4,5-dihydro-4-(1-Methylethyl)-, (4S)-
  • (4S)-2-[2-(Diphenylphosphino)phenyl]-4,5-dihydro-4-(1-methylethyl)oxazole,99%e.e.
  • (S)-2-(2-(diphenylphosphanyl)phenyl)-4-isopropyl-4,5-dihydrooxazole
  • (S)-iPr-Phox
  • (S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydroo
  • 148461-14-7
  • C24H24NOP
  • PHOX
  • Privileged Ligands
  • Chiral Catalysts, Ligands, and Reagents
  • Asymmetric Synthesis
  • Chiral Phosphine
  • PHOX Series
  • organophosphine ligand